Aluminium Chloride Molecule

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Atoms are the smallest particle of an element and are the basic building blocks of all matter. Atoms are composed of a nucleus which contain positively charged particles called protons and no charged particles called neutrons. Surrounding the nucleus are negatively charged electrons arranged in shells. These electrons exist in a cloud around the nucleus. When two electron clouds of different atoms interact, they bind together to form a molecule. An example of a molecular compound (a molecule that contains atleast two or more different elements) is Aluminium Chloride (AlCl2).

 

 

 
Aluminium Chloride consists of three Chloride atoms and one Aluminium atom which is shown in the image below. These atoms are structured in a trigonal planar with the three chlorine atoms surrounding the single aluminium atom with bonds, 120 degrees apart.The structure of the molecule is based upon temperature change. At temperatures around 190 degrees Celsius Aluminium Chloride converts to Al2Cl6. As temperatures increase further, the molecule is broken up into simple AlCl3  molecules. The aluminium and chloride atoms are bonded covalently, sharing electron pairs in the attractive and repulsive forces between the atoms. However this is only the case for the liquid or vapour form of Aluminium Chloride. When it is in solid form the atoms bond ionically, transferring electrons between atoms.
 
Aluminium atoms (Al) are composed of 13 protons and 14 neutrons  in its nucleus, and 13 electrons surrounding the nucleus. The  surrounding electrons are arranged in three shells, 2 in the first, 8 in the second and 3 in the third. Aluminium atoms are one of the lightest atoms with an atomic mass of 26.98 amu. Similarly, Chloride atoms have an atomic mass of 35.45 amu. Chloride atoms have 17 protons and 18 neutrons present in its nucleus and 17 electrons surrounding it in 3 shells. The first shell having 2 electrons, the second having 8 electrons and the third having 7 electrons.
 

 

Aluminium chloride has a number of characteristics that differentiate it from other molecules. Firstly the melting point of the molecule is 190 degrees celsius and the boiling point is 178 degrees celsius. In its solid state, Aluminium Chloride is a powdery form with varying colours based on contact with moisture and other substances. The most common colour is yellow. Moreover, in it’s solid form it’s density is 2.44 g. The molecule is relatively stable but when water is applied to solid aluminium chloride, a violent reaction occurs with the production of steamy fumes of hydrogen chloride gas. Aluminium Chloride is most commonly used to control excessive sweating in the form of an antiperspirant. When applied to skin, aluminium chloride salt dissolves from the sweat or moisture of the skin surface forming an acidic solution that diffuses into the sweat glands. Then metal ions precipitate and the aluminium chloride hydrolyses in more alkaline sweat, forming a gel plug in the lumen of the sweat gland duct. This prevents pores from releasing sweat.

 

During my programming process of my molecule I found many interesting  aspects of the software, as well as difficulties. Firstly, I found the precision of the programming particularly interesting. If one letter or number was incorrect it caused the whole programme to disfunction. As my program was particularly long, it was especially difficult to find the small errors I had made and alter them. In addition, the idea of using an object, in this case a turtle, as a reference for placing other objects was also interesting. Every object placement, including the angle, shape, colour and direction, was based on the reference object. This made programming considerably easier to manage as a preview of our objects location was given. However with this reference function came a difficulty. No matter which direction the turtle was facing, the North, South, East and West (up, down, forward, backwards, etc.) directions never changed. For example, even if the turtle was upside down, if I commanded the turtle to move upwards it will always move where north was. Thus, I found it difficult at times to place the turtle in the location I wanted my object.

 
Links for further information:
Atoms, Molecules, Elements
http://www.ptable.com/
http://whatis.techtarget.com/definition/molecule
http://www.khanacademy.org/science/chemistry/atomic-structure-and-properties
 
 
Aluminium Chloride
https://www.cs.mcgill.ca/~rwest/wikispeedia/wpcd/wp/a/Aluminium_chloride.htm
http://www.chemicalland21.com/industrialchem/inorganic/ALUMINUM%20CHLORIDE.html
 
 
Aluminium Chloride Structure
http://glossary.periodni.com/glossary.php?en=trigonal+planar+molecular+geometry
http://www.chemguide.co.uk/atoms/bonding/covalent.html
http://www.chemicalelements.com/elements/al.html
 
Aluminium Chloride Uses
http://www.mayoclinic.org/diseases-conditions/hyperhidrosis/multimedia/sweat-glands/img-20007980
http://www.aluminumsulfate.net/Aluminum-Chloride.html
http://www.antiperspirantsinfo.com/en/antiperspirants-and-deodorants/about-antiperspirants-and-deodorants.aspx
http://www.sweathelp.org/treatments-hcp/topical-treatments/aluminum-chloride.html
 
Questions for Further Investigation and Discussion
 
Why does temperature change affect the structure of Aluminium Chloride?
-Is it possibly due to its chemical composition?
 
Why does Aluminium Chloride react violently with water?
 
How is Aluminium Chloride used , and what for, in relation to the Friedel-Crafts reactions?
-Could it have something to do with the molecule characterisation as a Lewis Acid?
 
 
 
 
Links to 3D Models and Programmes
 
AlCl3:
 
Al2Cl6: